μTorrent opens by itself every time Windows startup
Windows 10 Fall Creators Update is why μTorrent opens itself when the computer starts up.

Because when shutting down PC, any open apps are bookmarked and after reboot/restart, these apps will re-open automatically.

In other words, if you want μTorrent not to open itself, you need to be sure that the application is shut down to shut down before shutting down or restarting the PC.

The solution is to click on the chevron in the bottom right corner to "Show...

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